Coherent states formulation of polymer field theory.

نویسندگان

  • Xingkun Man
  • Kris T Delaney
  • Michael C Villet
  • Henri Orland
  • Glenn H Fredrickson
چکیده

We introduce a stable and efficient complex Langevin (CL) scheme to enable the first direct numerical simulations of the coherent-states (CS) formulation of polymer field theory. In contrast with Edwards' well-known auxiliary-field (AF) framework, the CS formulation does not contain an embedded nonlinear, non-local, implicit functional of the auxiliary fields, and the action of the field theory has a fully explicit, semi-local, and finite-order polynomial character. In the context of a polymer solution model, we demonstrate that the new CS-CL dynamical scheme for sampling fluctuations in the space of coherent states yields results in good agreement with now-standard AF-CL simulations. The formalism is potentially applicable to a broad range of polymer architectures and may facilitate systematic generation of trial actions for use in coarse-graining and numerical renormalization-group studies.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 140 2  شماره 

صفحات  -

تاریخ انتشار 2014